Career: Alongside theatre roles, Baldwin's early career included parts in TV series The Doctors, Cutter to Houston and Knots Landing. His first film was Forever, Lulu in 1987. A year later he starred in Beetlejuice (1988), and had smaller roles in Married to the Mob (1988), Working Girl (1988), Talk Radio (1988), and She's Having a Baby (1988). The Hunt for Red October in 1990 saw him take the lead alongside screen icon Sean Connery. He went on to appear in Glengarry Glen Ross (1992), The Getaway (1994), Pearl Harbor (2001), The Cooler (2003), The Departed (2006), The Good Shepherd (2006), Brooklyn Rules (2007), It's Complicated (2009) and Blue Jasmine (2013). He won a number of awards for his portrayal of Jack Donaghy in NBC sitcom 30 Rock between 2006 and 2013, was the host of a short-lived chat show called Up Late with Alec Baldwin and co-hosted the Oscars with Steve Martin in 2010. More recently, he has appeared in Mission: Impossible - Rogue Nation (2015), voiced lead character Timothy Templeton in The Boss Baby (2017) and appeared in an episode of Law and Order: Special Victims Unit. He also played Donald Trump on Saturday Night Live and received a Critics Choice Television Award for Best Guest Performer in a Comedy Series.

Career: Buscemi's early roles included several in experimental theatre, co-written by himself and fellow actor/writer Mark Boone Jr. He also appeared in Miami Vice, The Equalizer, and films The Way It Is, Tommy's and Parting Glances. He received excellent reviews for the latter, which led to parts in Lonesome Dove and New York Stories. He's since become a stalwart of indie movies thanks to his scene-stealing appearances in Reservoir Dogs, Miller's Crossing, Fargo and The Big Lebowski. Bigger-budget films include Armageddon, Con Air and The Wedding Singer. Buscemi has also written, directed, and produced several projects, and appeared in TV show The Sopranos. More recently he's played Enoch 'Nucky' Thompson in acclaimed drama Boardwalk Empire, for which he won a Golden Globe in 2011.

Career: Kimmel's TV career began in 1997 on the game show Win Ben Stein's Money, for which he and Ben Stein won an Emmy award for Best Game Show Host. He stayed with the show until 2001. Kimmel also hosted The Man Show before going on to host Jimmy Kimmel Live!, his own late-night talk show which has run since 2003. He has also appeared on a number of other talk shows, including The Ellen DeGeneres Show and The Late Show with David Letterman. Kimmel also created The Andy Milonakis Show, which ran from 2005 to 2007. He has had cameos in a number of films, including Hellboy II: The Golden Army (2008), Pitch Perfect 2 (2015) and Ted 2 (2015). He also voiced Passive Aggressive Smurf in The Smurfs 2 (2013) and Ted Templeton in The Boss Baby (2017).

Career: Started out with Los Angeles improvisational theatre group The Groundlings, and her first big TV break came in the sitcom Mad About You, playing feisty waitress Ursula. Since then, Friends has made her a familiar face to millions across the globe. She has also appeared in several movies, including Analyze This, and the sequel Analyze That, with Billy Crystal and Robert De Niro, and The Opposite of Sex, which won her a prestigious New York Film Critics Award. In 2005, she appeared in short-lived sitcom The Comeback.

Career: Maguire left school early and began gaining small roles in advertisements and TV shows. He had a regular role in sitcom Great Scott! in 1992, and went on to appear in such acclaimed films as This Boy's Life (opposite good friend Leonardo DiCaprio), The Ice Storm and Deconstructing Harry. Ride with the Devil, Pleasantville and The Cider House Rules proved he was more than just a pretty face and put him on the map. Since then he's appeared in Wonder Boys, Ride with the Devil, Seabiscuit, Spider-Man, together with its two hugely successful sequels, Brothers and, again with DiCaprio, The Great Gatsby.